FISHER SCIENTIFIC, CHEMICAL DIV. -- 11189 HYDROGEN PEROXIDE 30-50% -- 6810-00-233-1711 
=====================  Product Identification  =====================

Product ID:11189 HYDROGEN PEROXIDE 30-50%
MSDS Date:04/21/1999
FSC:6810
NIIN:00-233-1711
Status Code:A
=== Responsible Party ===
Company Name:FISHER SCIENTIFIC, CHEMICAL DIV.
Address:1 REAGENT LANE
City:FAIR LAWN
State:NJ
ZIP:07410
Country:US
Info Phone Num:201-796-7100 OR 201-796-7523
Emergency Phone Num:201-796-7100
Chemtrec Ind/Phone:(800)424-9300
CAGE:1B464
=== Contractor Identification ===
Company Name:APA INDUSTRIES INC
Address:5309 BOUGHNER ROAD
Box:City:ROCK CREEK
State:OH
ZIP:44084
Country:US
Phone:800-424-9300(CHEMTREC)
CAGE:4Y971
Company Name:FISHER SCIENTIFIC CO
Address:2000 PARK LN
Box:City:PITTSBURGH
State:PA
ZIP:15275
Country:US
Phone:412-490-8586
CAGE:22527
Company Name:FISHER SCIENTIFIC CO
Address:3970 JOHNS CREEK CT, SUITE 500
Box:City:SUWANEE
State:GA
ZIP:30024
Country:US
Phone:770-871-4500
Contract Num:SP0450-00-M-D438
CAGE:8E930
Company Name:FISHER SCIENTIFIC CO
Address:3970 JOHNS CREEK CT, SUITE 500
Box:City:SUWANEE
State:GA
ZIP:30024
Country:US
Phone:770-871-4500
Contract Num:SP0450-01-M-D598
CAGE:8E930
Company Name:FISHER SCIENTIFIC CO.  CHEMICAL MFG DIV
Address:1 REAGENT LANE
Box:City:FAIRLAWN
State:NJ
ZIP:07410-2802
Country:US
Phone:201-796-7100
CAGE:1B464

=============  Composition/Information on Ingredients  =============

Ingred Name:HYDROGEN PEROXIDE (SARA 302)
CAS:7722-84-1
RTECS #:MX0900000
Minumum % Wt:30.
Maxumum % Wt:50.
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1 PPM
ACGIH TLV:1 PPM; 9596

Ingred Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: BALANCE
Other REC Limits:NONE RECOMMENDED

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:ORAL, RAT LD50:>90ML/KG.
Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:NO
Reports of Carcinogenicity:NTP:NO    IARC:YES	 OSHA:NO
Health Hazards Acute and Chronic:EYE: CONTACT WITH LIQUID IS  CORROSIVE
    TO EYES. CAUSES SEVERE BURNS. MAY CAUSE CORNEAL DAMAGE. SKIN:
    CAUSES SEVERE SKIN IRRITATION, POSSIBLE BURNS & DISCOLORATION,
    ERYTHEMA, SWELLING, THE FORMATION OF  PAPULES & VESICLES.
    INGESTION: CAUSES GASTROINTESTINAL IRRITATION AND GASTROINTESTINAL
    TRACT BURNS, MAY CAUSE VASCULAR COLLAPSE AND DAMAGE. MAY CAUSE
    DAMAGE TO RED BLOOD CELLS. DIFFICULTY IN SWALLOWI NG, STOMACH
    DISTENSION, POSSIBLE CEREBRAL SWELLING & DEATH. INGESTION MAY
    RESULT IN IRRITATION OF THE ESOPHAGUS, BLEEDING OF THE STOMACH AND
    ULCER FORMATION. INHALATION: CAUSES BURNS TO RESPIRATORY TR ACT,
    ULCERATION OF NASAL TISSUE.
Explanation of Carcinogenicity:PER MSDS:HYDROGEN PEROXIDE:IARC:GROUP 3
    CARCINOGEN.
Effects of Overexposure:EYE:CORROSIVE & CAUSES SEVERE BURNS, POSSIBLY
    CORNEAL DAMAGE. SKIN: SEVERE IRRITATION, POSSIBLE BURNS,
    DISCOLORATION, ERYTHEMA, SWELLING & FORMATION OF PAPULES &
    VESICLES. INGESTION:  GASTROINTESTINAL  IRRITATION WITH NAUSEA,
    VOMITING, & DIARRHEA, GASTROINTESTINAL TRACT BURNS, VASCULAR
    COLLAPSE & DAMAGE, DIFFICULTY IN SWALLOWING, STOMACH DISTENSION,
    CEREBRAL SWELLING & DEATH, IRRITATION OF ESOPHAGU S, BLEEDING OF
    THE STOMACH & ULCER FORMATION. INHALATION: CHEMICAL BURNS TO
    RESPIRATORY TRACT, ULCERATION OF NASAL TISSUE, INSOMNIA, NERVOUS
    TREMORS WITH NUMB EXTREMITIES, CHEMICAL PNEUMONIA, UNCONSCI
    OUSNESS/DEATH.
Medical Cond Aggravated by Exposure:NO DATA PROVIDED BY MANUFACTURER.

=======================  First Aid Measures  =======================

First Aid:EYE: GET MEDICAL AID IMMEDIATELY. DO NOT ALLOW VICTIM TO RUB
    OR KEEP EYES CLOSED. EXTENSIVE IRRIGATION IS REQUIRED. SKIN: GET
    MEDICAL AID IMMEDIATELY. FLUSH WITH PLENTY OF SOAP & WATER FOR AT
    LEAST 15  MINUTES WHILE REMOVING CONTAMINATED CLOTHING/SHOES. 
    INGESTION: DO NOT INDUCE VOMITING. IF VICTIM IS CONSCIOUS & ALERT,
    GIVE 2-4 CUPFULS OF MILK OR WATER. NOTHING BY MOUTH TO AN
    UNCONSCIOUS PERSON. G ET MEDICAL AID IMMEDIATELY. WASH MOUTH OUT
    WITH WATER. IF VOMITING OCCURS & THE VICTIM IS CONCIOUS, GIVE
    WATER. INHALED: GET IMMEDIATE MEDICAL AID. REMOVE FROM EXPOSURE. IF
    BREATHING DIFFICULT, GIVE O XYGEN. DO NOT GIVE MOUTH-TO-MOUTH.

=====================  Fire Fighting Measures  =====================

Flash Point:NON-COMBUSTIBLE
Autoignition Temp:Autoignition Temp Text:NONCOM
Lower Limits:40
Upper Limits:100
Extinguishing Media:USE WATER ONLY. DO NOT USE CARBON DIOXIDE. DO NOT
    USE DRY CHEMICAL. DO NOT GET WATER INSIDE CONTAINERS.
Fire Fighting Procedures:WEAR A SELF-CONTAINED BREATHING APPARATUS IN
    PRESSURE DEMAND, MSHA/NIOSH (APPROVED OR EQUIVALENT), AND FULL
    PROTECTIVE GEAR. WATER RUNOFF CAN CAUSE ENVIRONMENTAL DAMAGE. DIKE
    AND COLLECT WATER USED TO  FIGHT FIRE. STRONG OXIDIZER. CONTACT
    WITH COMBUSTIBLE MATERIAL MAY CAUSE A FIRE.
Unusual Fire/Explosion Hazard:STRONG OXIDIZER. CONTACT WITH COMBUSTIBLE
    MATERIALS MAY CAUSE FIRE. SOME OXIDIZERS MAY REACT EXPLOSIVELY WITH
    HYDROCARBONS (FUEL).

==================  Accidental Release Measures  ==================

Spill Release Procedures:AVOID RUNOFF TO STORM SEWERS AND DITCHES WHICH
    LEAD TO WATERWAYS. CLEAN UP SPILL IMMEDIATELY. USE WATER SPRAY TO
    DISPERSE THE GAS/VAPOR. REMOVE ALL SOURCES OF IGNITION. ABSORB
    SPILL USING AN ABSORBENT , NON-COMBUSTIBLE MATERIAL (EARTH, SAND,
    VERMICULITE). FLUSH AREA WITH WATER. PROVIDE VENTILATION. DO NOT
    GET WATER INSIDE CONTAINERS. KEEP COMBUSTIBLES AWAY FROM SPILLED
    MATERIAL
Neutralizing Agent:NO DATA PROVIDED BY MANUFACTURER.

======================	Handling and Storage  ======================

Handling and Storage Precautions:USE ONLY IN WELL VENTILATED AREA. 
    CONTENTS MAY DEVELOP PRESSURE ON PROLONGED STORAGE. DO NOT GET IN
    EYES, ON SKIN OR ON CLOTHES. AVOID CONTACT WITH COMBUSTIBLE
    MATERIALS. DO NOT INGEST OR INHALE. STO RE PROTECTED FROM LIGHT.
    UNUSED MATERIALS SHOULD NOT BE RETURNED TO CONTAINER.
Other Precautions:KEEP AWAY FROM HEAT, SPARKS, FLAME. DO NOT STORE NEAR
    COMBUSTIBLE MATERIALS. KEEP CONTAINER CLOSED WHEN NOT IN USE. STORE
    IN A COOL, DRY, WELL-VENTILATED AREA AWAY FROM INCOMPATIBLES. STORE
    BELOW 35C.	STORE ONLY IN LIGHT RESISTENT CONTAINERS FITTED WITH
    SAFETY VENT. RINSE EMPTY CONTAINERS THOROUGHLY  BEFORE DISCARDING.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA
     29 CFR 1910.134 AND ANSI Z88.2 REQUIREMENTS OR EUROPEAN STANDARD
    EN 149 MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A
    RESPIRATOR'S USE.
Ventilation:USE EXPLOSION-PROOF VENTILATION EQUIPMENT. USE ADEQUATE
    GENERAL OR LOCAL EXHAUST VENTILATION.
Protective Gloves:CHEMICAL SAFETY GLOVES
Eye Protection:EYEGLASSES OR CHEMICAL SAFETY GOGGLES
Other Protective Equipment:WEAR APPROPRIATE PROTECTIVE CLOTHING TO
    PREVENT SKIN CONTACT. EYE WASH FACILITY AND SAFETY SHOWER.
Work Hygienic Practices:WASH CONTAMINATED CLOTHES BEFORE REUSE. DESTROY
    CONTAMINATED SHOES
Supplemental Safety and Health
NO DATA PROVIDED BY MANUFACTURER

==================  Physical/Chemical Properties  ==================

HCC:D3
Boiling Pt:=108.C, 226.4F
Melt/Freeze Pt:=-33.C, -27.4F
Decomp Temp:Decomp Text:N/AVAIL
Vapor Pres:23 @30C
Vapor Density:1.10
Spec Gravity:3.3 (30%SOLUTION)
pH:2.5-3.5
Viscosity:1.25CP
Evaporation Rate & Reference:>1.0 (N-BUTYL ACETATE=1)
Solubility in Water:MISCIBLE.
Appearance and Odor:CLEAR, COLORLESS, LIQUID, ODOR:SLIGHT ACRID
Percent Volatiles by Volume:NP
Corrosion Rate:NP

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, STRONG REDUCING AGENTS, ACETIC ACID, ALKALINE
    MATERIALS,	H3COOH,(CH3C0)2O,ACETONE,ALCOHOLS,H2SO4,(SUPL)
Stability Condition to Avoid:DECOMPOSES SLOWLY TO RELEASE OXYGEN.
    MECHANICAL SHOCK,  LIGHT, IGNITION SOURCES, DUST GENERATION, EXCESS
    HEAT
Hazardous Decomposition Products:OXYGEN, HYDROGEN GAS.
Conditions to Avoid Polymerization:WILL NOT OCCUR.

===================  Toxicological Information	===================

Toxicological Information:LD50/LC50: CAS# 7722-84-: INHALATION, RAT
    LC50 = 2 GM/M3/4H; ORAL, MOUSE: LD50 = 2 GM/KG; SKIN, RAT: LD50 =
    4060 MG/LG. EPIDEMIOLOGY: NO INFORMATION AVAILABLE. TERATOGENICITY:
    NO INFORMATION AVAILABLE . REPRODUCTIVE EFFECTS: NO INFORMATION
    AVAILABLE.. NEUROTOXICITY: NO INFORMATION AVAILABLE.. MUTAGENICITY:
    CAS# 7722-84-1 MUTATION IN MICROORGANISMS: SALMONELLA TYPHIMURIUM =
    100 UG/PLATE; HYMAN EMBRY O = 50 UMOL/L; CYTOGENIC ANALYSIS: HUMAN
    EMBRYO  = 20 UMOL/L.MUTATION IN MAMMALIAN SOMATIC CELLS: HAMSTER,
    LUNG = 1 MMOLL/L. OTHER STUDIES: NO DATA AVAILABLE.

=====================  Ecological Information  =====================

Ecological:ECOTOXICITY: NOT AVAILABLE. FISH CARP: LC50 = 42 MG/L; 48
    HR, UNSPECIFIED. FISH: FATHEAD MINNOW: LC50 = 16.4 MG/L; 96 HR;
    FRESH WATER. FISH: FATHEAD MINNOW: NOEC = 5 MG/L; 96 HR; FRESH
    WATER. WATER FL EA DAPHNIA: EC50 = 2.4 MG/L; 48 HR; FRESH
    WATER.FISH: CHANNEL CATFISH: LC50 = 37.4 MG/L; 96 HR; FRESH WATER.
    ENVIRONMENTAL FATE: RAIN WASHOUT IS EXPECTED DUE TO CONDENSATION OF
    HYDROGEN PEROXIDE ON CO NTACT WITH WATER DROPLETS. IN ATMOSPHERE,
    PHOTOOXIDATION IS PERDICTED WITH 1/2 LIFE OF 10-20 HOURS.
    NON-SIGNIFIGANT EVAPORATION & ABSORPTION FROM WATER SURFACES &
    SOIL/SEDIMENTATION IS EXPECTED.

====================  Disposal Considerations  ====================

Waste Disposal Methods:DISPOSE OF IN MANNER CONSISTENT WITH FEDERAL,
    STATE AND LOCAL REGULATIONS (DLA-HMIS)

===================  MSDS Transport Information  ===================

Transport Information:US DOT: SHIPPING NAME: HYDROGEN PEROXIDE, AQUEOUS
    OSLUTIONS 30%. HAZARD CLASS: 5.1. UN NUMBER: UN2014. PACKING GROUP:
    II. CANADIAN TDG: SHIPPING NAME: HYDROGEN PEROXIDE. HAZARD CLASS:
    5.1(8). UN NUMBE R: UN2014.

=====================  Regulatory Information  =====================

SARA Title III Information:SARA SECTION 302 (RQ): NONE OF THE CHEMICALS
    IN THIS MATERIAL HAVE AN RQ. SARA SECTION 302 (TPQ): CONCENTRATIONS
    >52%: CAS# 7722-84-1, TPQ = 1000 LBS; RQ = 1000 LBS. SARA CODES:
    CAS# 7722-84-1: ACUTE,  FLAMMABLE. SECTION 313: NO CHEMICALS ARE
    REPORTABLE UNDER SECTION 313.
Federal Regulatory Information:CLEAN AIR ACT: THIS MATERIAL DOES NOT
    HAVE ANY HAZARDOUS AIR POLLUTANTS (HAP), ANY CLASS 1 OZONE
    DEPLETORS, ANY CLASS 2 OZONE DEPLETORS. CLEAN WATER ACT: NONE OF
    THE CHEMICALS IN THIS PRODUCT ARE LIST ED AS HAZARDOUS SUBSTANCES,
    PRIORITY POLLUTANTS OR TOXIC POLLUTANTS UN DER THE CWA. OSHA: CAS#
    7722-84-1 IS CONSIDERED HIGHLY HAZARDOUS BY OSHA. TSCA: CAS#'S
    7722-84-1 AND 7732-18-5 ARE LISTED ON THE  TSCA INVENTORY. HEALTH &
    SAFETY REPORTING LIST: NONE OF THE CHEMICLS IN THIS PRODUCT ARE ON
    THE HEAL TH & SAFETY REPORTING LIST. CHEMICAL TEST RULES: NONE OF
    THE CHEMICLS IN THIS PRODUCT ARE UNDER A CHEMICAL TEST RULE.
State Regulatory Information:HYDROGEN PEROXIDE CAN BE FOUND ON THE
    FOLLOWING SATE RIGHT TO KNOW LISTS: CALIFORNIA, NEW JERSEY,
    FLORIDA, PENNSYLVANIA, MINNESOTA, MASSACHUSETTS. WATER IS NOT
    PRESENT  ON STATE LISTS FROM CA, PA, MN,  MA, FL OR NJ. CALIFORNIA
    NO SIGNIFIGANT RISK LEVEL: NONE OF THE CHEMICALS IN THIS PRODUCT
    ARE LISTED.

=======================  Other Information  =======================

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