ZYNOLYTE PRODUCTS CO -- 0182 CHOCOLATE BROWN, AEROSOL SPRAY PAINTS, (SUPDAT)  -- 8010-00N071152
<pre>=====================  Product Identification  =====================

Product ID:0182 CHOCOLATE BROWN, AEROSOL SPRAY PAINTS, (SUPDAT)
MSDS Date:10/02/1989
FSC:8010
NIIN:00N071152
=== Responsible Party ===
Company Name:ZYNOLYTE PRODUCTS CO
Address:2320 E DOMINGUEZ ST
City:CARSON
State:CA
ZIP:90749-6244
Country:US
Info Phone Num:310-513-0700
Emergency Phone Num:800-424-9300 (CHEMTREC)
CAGE:25461
=== Contractor Identification ===
Company Name:ZYNOLYTE PRODUCTS CO
Address:2320 E DOMINGUEZ ST
Box:6244
City:CARSON
State:CA
ZIP:90749
Country:US
Phone:310-513-0700
CAGE:25461

=============  Composition/Information on Ingredients  =============

Ingred Name:SOLVENT NAPHTHA (PETROLEUM), LIGHT AROMATIC; (AROMATIC
    HYDROCARBON). VP:10 @ 20C.
CAS:64742-95-6
RTECS #:WF3400000
OSHA PEL:25 PPM (MFR)
ACGIH TLV:25 PPM (MFR)

Ingred Name:ACETIC ACID, BUTYL ESTER; (BUTYL ACETATE) (CERCLA). VP:8 @
    20C.
CAS:123-86-4
RTECS #:AF7350000
OSHA PEL:150 PPM
ACGIH TLV:150 PPM;200 STEL
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS

Ingred Name:CARBON BLACK
CAS:1333-86-4
RTECS #:FF5800000
OSHA PEL:3.5 MG/M3
ACGIH TLV:3.5 MG/M3

Ingred Name:ARIEN
CAS:64742-16-1
RTECS #:CF2550000
OSHA PEL:N/K 
ACGIH TLV:N/K 

Ingred Name:IRON (III) OXIDE; (IRON OXIDE)
CAS:1309-37-1
RTECS #:NO7400000
OSHA PEL:10 MG/M3 (FE)
ACGIH TLV:5 MG/M3 FUME (FE)

Ingred Name:PROPANE; (LIQUIFIED COMPRESSED GAS)
CAS:74-98-6
RTECS #:TX2275000
OSHA PEL:1000 PPM
ACGIH TLV:ASPHYXIANT

Ingred Name:SOLVENT NAPHTHA (PETROLEUM) MEDIUM ALIPHATIC; (MEDIUM
    MINERAL SPIRITS)
CAS:64742-88-7
OSHA PEL:N/K 
ACGIH TLV:N/K 

Ingred Name:METHANE, DICHLORO-; (METHYLENE CHLORIDE)  (SARA 313)
    (CERCLA). VP:340 @ 20C.
CAS:75-09-2
RTECS #:PA8050000
OSHA PEL:500 PPM
ACGIH TLV:50 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS

Ingred Name:BUTYL ALCOHOL; (N-BUTYL ALCOHOL)  (SARA 313) (CERCLA).
    VP:5.5 @ 20C.
CAS:71-36-3
RTECS #:EO1400000
OSHA PEL:100 PPM
ACGIH TLV:50 PPM, S, C
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS

Ingred Name:SILICA, CRYSTALLINE - QUARTZ; (QUARTZ-CRYSTALLINE SILICA)
CAS:14808-60-7
RTECS #:VV7330000
OSHA PEL:0.1 MG/M3 (MFR)
ACGIH TLV:0.1 MG/M3 RDUST

Ingred Name:SILICONE RESIN
OSHA PEL:N/K 
ACGIH TLV:N/K 

Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE)
CAS:13463-67-7
RTECS #:XR2275000
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST

Ingred Name:TOLUENE (SARA 313) (CERCLA). VP:36.7 @ 20C.
CAS:108-88-3
RTECS #:XS5250000
OSHA PEL:200 PPM
ACGIH TLV:50 PPM, S
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS

Ingred Name:VM & P NAPHTHA
CAS:64742-89-8
Other REC Limits:100 PPM (MFR)
OSHA PEL:N/K 
ACGIH TLV:300 PPM (MFR)

Ingred Name:XYLENE  (SARA 313) (CERCLA). VP:25 @ 20C.
CAS:1330-20-7
RTECS #:ZE2100000
OSHA PEL:100 PPM
ACGIH TLV:100 PPM;150 STEL
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS

Ingred Name:SUPDAT:QUARTZ:IARC MONOGRAPHS, SUPP, VOL 7, PG 341,
    1987:GRP 2A. NTP 7TH ANNUAL RPT ON CARCINS, 1994:ANTIC TO BE
    CARCIN.
RTECS #:9999999ZZ

Ingred Name:EFTS OF OVEREXP:APPROP HLTH PROFESSIONALS CONCERNING LATEST
    HAZ LIST INFO & SAFE HNDLG & EXPOS INFO . (ING 18)
RTECS #:9999999ZZ

Ingred Name:ING 17:ING 1:LAB ANIMALS:TOX TO FETUS AT DOSES TOX TO
    MOTHER. INGS 1,2,8,13,15:LIVER & KIDNEY INJURY. INGS 6,8: (ING 19)
RTECS #:9999999ZZ

Ingred Name:ING 18:SKIN BURNS. ING 6:MODEST INITIAL IRRIT, FOLLOWED BY
    SHORTNESS OF BREATH, REQUIRING PROMPT MED ATTN. CNS (ING 20)
RTECS #:9999999ZZ

Ingred Name:ING 19:(TEMPORARY MUSCULAR WEAK & LOSS OF COORD). EYE CORR
    & PERM INJURY. INGS 7,14:RATS:KIDNEY DMG & KIDNEY/ (ING 21)
RTECS #:9999999ZZ

Ingred Name:ING 20:LIVER TUMORS (NO SIGNIFICANT INCRS IN PETRO
    WORKERS). INGS 8,15:SKIN ABSORP:HARMFUL. ING 8:INCR IN (ING 22)
RTECS #:9999999ZZ

Ingred Name:ING 21:CARBOXYHEMOGLOBIN LEVELS RSLTG IN REDUCED LEVEL OF
    OXYG IN BLOOD. MUTAGENIC ACTIVITY. ING 9:EYE:CHEM (ING 23)
RTECS #:9999999ZZ

Ingred Name:ING 22:BURNS. ABNORM LIVER/KIDNEY & BLOOD FORMING FUNC
    W/ANEMIA. ING 10:TYPICAL X-RAY CHANGES & CHRONIC LUNG (ING 24)
RTECS #:9999999ZZ

Ingred Name:ING 23:DISEASE. ING 12:RATS:LUNG CANCER-NOT RELEVANT TO
    WORKPLACE. ING 13:IRREG HEART BEATS-ANIMALS; OCCAS (ING 25)
RTECS #:9999999ZZ

Ingred Name:ING 24:PALPITATIONS-HUMANS. RATS:HIGH FREQUENCY HEARING
    DEFICITS-SIGNIFICANCE TO MAN UNKNOWN. ING 15:ANIMALS:EMBRYOTOX.
RTECS #:9999999ZZ

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:YES
Reports of Carcinogenicity:NTP:YES    IARC:YES	  OSHA:NO
Health Hazards Acute and Chronic:CHLOROCARBON MATLS HAVE PRDCD SENSIT
    OF MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS & COULD HAVE SIMILAR
    EFT IN HUMANS. ADRENOMIMETICS (E.G., EPINEPHRINE) MAY BE
    CONTRAINDICATED EXCEPT FOR LIFE-SUSTAININ G USES IN HUMANS
    ACUTELY/CHRONICALLY EXPOS TO CHLOROCARBONS . INGEST:GI DISTRESS.
    INHAL:NOSE & (EFTS OF OVEREXP)
Explanation of Carcinogenicity:CARBON BLACK:IARC MONO ON EVAL OF CARCIN
    RISK OF CHEMS TO MAN, VOL 65, PG 24-27, 1995:GRP 2B. METHYLENE
    (SUPP DATA)
Effects of Overexposure:HLTH HAZ:THROAT IRRIT; CNS EFTS(DIZZ, HDCH,
    NAUS, STAG GAIT, CONFUSN, UNCON); EYE WATERING, LOSS OF COORD. RPTS
    HAVE ASSOC RPTD & PRLNG OVEREXP TO SOLVS W/PERM BRAIN NERV SYS DMG.
    SKIN:IRRIT, DISCOMFO RT, DERM. EYES:IRRIT/BURNING. NOTE:TOLUENE
    APPEARS ON NAVY LIST OF OCCUP CHEM REPRO HAZS. SEEK CONSULTATION
    FROM(ING 17)
Medical Cond Aggravated by Exposure:HEAVY SMOKERS & THOSE W/HEART
    DISEASE MAY EXPERIENCE INCREASE RISK OF HEART PROBLEMS.

=======================  First Aid Measures  =======================

First Aid:INGEST:CALL MD IMMEDIATELY & HAVE NAMES OF INGREDIENTS
    AVAILABLE. DO NOT INDUCE VOMITING. INHAL:REMOVE TO FRESH AIR. IF
    NOT BREATHING, GIVE ARTIFICIAL RESPIRATION, PERFERABLY MOUTH TO
    MOUTH. IF BREATH ING DIFFICULTY PERSISTS/OCCURS LATER, CONSULT MD.
    EYES:IMMEDIATELY FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINUTES;
    CALL MD. SKIN:WASH W/SOAP & WATER. IF IRRITATION OCCURS CONTACT MD.

=====================  Fire Fighting Measures  =====================

Flash Point Method:CC
Flash Point:<20F,<-7C
Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH APPRVD PRESS DEMAND SCBA & FULL
    PROT EQUIP . WATER MAY BE INEFT. WATER FROM FOG NOZZ MAY BE USED TO
    COOL CLSD CNTNRS TO PVNT PRESS BUILD UP.
Unusual Fire/Explosion Hazard:THERMAL DECOMP PRODS MAY INCL HCL &
    PHOSGENE . CONTENTS UNDER PRESS. KEEP AT ROOM TEMP AS EXPOS TO
    SUNLIGHT/OTHER HEAT MAY CAUSE CANS TO BURST, (SUPDAT)

==================  Accidental Release Measures  ==================

Spill Release Procedures:VENTILATE AREA. REMOVE SOURCES OF IGNITION.
    PREVENT SKIN CONTACT & BREATHING OF VAPORS. CONFINE & REMOVE
    W/INERT ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

======================	Handling and Storage  ======================

Handling and Storage Precautions:DO NOT BREATHE VAPS/MISTS. KEEP AWAY
    FROM HEAT, SPKS & FLAME. DO NOT STORE >120F. DO NOT PUNCTURE. DO
    NOT SPRAY NEAR FIRE/OPEN FLAME.
Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN GEN VICIN OF
    ARC WELDING, OPEN FLAMES/HOT SURFS. HEAT &/OR UV RADIA MAY CAUSE
    FORM OF HCL &/OR PHOSGENE . OBSERVE LABEL PRECAUTIONS. DO NOT
    EXPOSE TO DIR ECT SUNLIGHT TO AVOID BURSTING.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:NIOSH APPROVED RESPIRATOR APPROPRIATE FOR
    EXPOSURE OF CONCERN . FOR MORE SPECIFIC INFORMATION CONTACT NEHC .
Ventilation:PROVIDE SUFFICIENT VENTILATION IN VOLUME & PATTERN TO KEEP
    CONTAMINANTS BELOW APPLICABLE OSHA REQUIREMENTS.
Protective Gloves:NEOPRENE GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS &(SUPDAT)
Other Protective Equipment:ANSI APPRVD EYE WASH FOUNTAIN & DELUGE
    SHOWER . COVERALLS; PROT CREAMS - USED FOR EASE OF CLEAN-UP, NOT
    FOR PROT.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING & BEFORE EATING
    & SMOKING.
Supplemental Safety and Health
MFR'S TRADE NAME/PART #:SPRAY MATE. EXPLO HAZ:PROPELLING CONTENTS
    ACROSS AREA. EYE PROT:FULL LGTH FCSHLD. EXPLAN OF
    CARCIN:CHLORIDE:IARC MONO, SUPP, VOL 7, PG 194, 1987:GRP 2B. NTP
    7TH ANNUAL RP T ON CARCINS, 1994:ANTIC TO BE CARCIN. ANIMAL:LUNG,
    LIVER, SALIVARY, MAMMARY GLAND(TUMORS). SILICA, CRYSTALLINE-(ING
    16)

==================  Physical/Chemical Properties  ==================

Boiling Pt:B.P. Text:<0F,<-18C
Vapor Pres:SEE INGS
Vapor Density:HVR/AIR
Spec Gravity:0.74 
Evaporation Rate &amp; Reference:FASTER THAN ETHER
Solubility in Water:MOD - APPRECIABLE
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:92

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
METHYLENE CHLORIDE CAN CHEMICALLY REACT W/ALUMINUM CAUSING EXPLO HAZ &
    VIOLENT RXN. FOR MORE INFO CONT NEHC .
Stability Condition to Avoid:DO NOT STORE ABOVE 120F.
Hazardous Decomposition Products:HCL, PHOSGENE . CO, CO*2, SMOKE,
    OXIDES OF HEAVY METALS REPORTED IN INGREDIENTS SECTION.

====================  Disposal Considerations  ====================

Waste Disposal Methods:DO NOT ALLOW MATERIAL TO CONTAMINATE GROUND
    WATER SYSTEMS. INCINERATE ABSORBED MATERIAL I/A/W FEDERAL, STATE &
    LOCAL REQUIREMENTS. DO NOT INCINERATE IN CLOSED CONTAINERS.

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 of Defense.  The United States of America in no manner whatsoever,
 expressly or implied, warrants this information to be accurate and
 disclaims all liability for its use.  Any person utilizing this
 document should seek competent professional advice to verify and
 assume responsibility for the suitability of this information to their
 particular situation.